Valence shell direct double photodetachment in polyanions

Multiple Electron Ejection from Proteins Resulting from Single-Photon Excitation in the Valence Shell.

One-photon multiple ionization is a signature of dynamical electron correlations in atoms and small molecules, as observed in the Auger process when Auger electron emission follows core-shell ionization. In such a process, the high energy needed to remove several electrons is due to the strong Coulombic attraction between the last departing electron(s) and the ionic core. Multiply negatively ch...

Studies of valence shell photoionization of Cl2

Stabilization of nuclear isovector valence-shell excitations.

Excited states in 138Ce have been studied via the 12C(138Ce, 138Ce*) Coulomb excitation reaction at 480 MeV. Relative cross sections have been determined from the gamma-ray yields observed with Gammasphere. The E2 and M1 strength distributions between the lowest six 2+ states up to 2.7 MeV enables us to identify the 2(4)+ state in 138Ce as the dominant fragment of the one-phonon 2(1,ms)+ mixed-...

Time delay in valence shell photoionization of noble gas atoms

We use the non-relativistic random phase approximation with exchange to perform calculations of valence shell photoionization of Ne, Ar, Kr and Xe from their respective thresholds to photon energy of 200 eV. The energy derivative of the complex phase of the photoionization matrix elements is converted to the photoelectron group delay that can be measured in attosecond streaking or twophoton tra...

Low-energy nondipole effects in molecular nitrogen valence-shell photoionization.

Observations are reported for the first time of significant nondipole effects in the photoionization of the outer-valence orbitals of diatomic molecules. Measured nondipole angular-distribution parameters for the 3sigma(g), 1pi(u), and 2sigma(u) shells of N2 exhibit spectral variations with incident photon energies from thresholds to approximately 200 eV which are attributed via concomitant cal...